The Chemical Composition and Dynamics of Titan’s Atmosphere as Revealed by ALMA
Alexander Thelen, NMSU
Over the last century, remarkable advances in our understanding of Titan’s atmosphere have been accomplished by a campaign of ground- and space-based observations revealing a wealth of complex, organic species in the moon’s upper atmosphere. Many of Titan’s atmospheric constituents produced through the photochemistry and ionospheric interactions of N2 and CH4 exhibit significant variations with latitude and time, particularly towards the poles and within the winter circumpolar vortex. The measurement of spatial and temporal variations in Titan’s atmosphere enables us to elucidate connections between its dynamics, photochemistry, and the influence of seasonal changes. At the end of the Cassini mission in 2017, we can employ the Atacama Large Millimeter/submillimeter Array (ALMA) for future observations of Titan’s atmosphere. Here we detail the analysis of numerous short integration (~3 minute) ALMA observations from 2012 to 2015 to investigate Titan’s stratospheric composition, temporal variations, and search for new molecular species. Using the Non-linear optimal Estimator for MultivariatE spectral analySIS (NEMESIS) radiative transfer code, we retrieved vertical profiles of temperature and abundance in Titan’s lower stratosphere through mesosphere (~50–550 km) from three spatially independent regions. We modeled CO emission lines to obtain temperature measurements, and retrieved abundance profiles for HCN, HC3N, C3H4, and CH3CN. The combination of integrated flux maps and vertical atmospheric profiles from spatially resolved observations allowed us to study the circulation of Titan’s middle atmosphere during northern spring. We observed increased temperatures in Titan’s stratopause at high northern latitudes and a persistent northern enrichment of HCN, C3H4, and CH3CN during this epoch; however, increased abundances of all molecules in the southern mesosphere, particularly HCN, and spatial maps of HC3N also show evidence for subsidence at the south pole. We validated these measurements through direct comparisons with contemporaneous Cassini data, previous ground-based observations, and photochemical model results. While no new trace species were detected, ALMA has proven to be a highly capable asset to enhance the data from the final few years of the Cassini mission, and for the continued study of Titan’s atmospheric dynamics, composition, and chemistry into Titan’s northern summer.