Characterization of Biosignatures within Geologic Samples Analyzed using a Suite of in situ Techniques
Kyle Uckert, NMSU
I investigated the biosignature detection capabilities of several in situ techniques to evaluate their potential to
detect the presence of extant or extinct life on other planetary surfaces. These instruments included: a laser desorption
time-of- flight mass spectrometer (LD-TOF-MS), an acousto-optic tunable filter (AOTF) infrared (IR) point spectrometer, a
laser-induced breakdown spectrometer (LIBS), X-ray diffraction (XRD)/X-ray fluorescence (XRF), and scanning electron
microscopy (SEM)/energy dispersive X-Ray spectroscopy (EDS). I measured the IR reflectance spectra of several speleothems
in caves in situ to detect the presence of biomineralization. Microorganisms (such as those that may exist on other solar
system bodies) mediate redox reactions to obtain energy for growth and reproduction, producing minerals such as
carbonates, metal oxides, and sulfates as waste products. Microbes occasionally become entombed in their mineral
excrement, essentially acting as a nucleation site for further crystal growth. This process produces minerals with a
crystal lattice distinct from geologic precipitation, detectable with IR reflectance spectroscopy. Using a suite of
samples collected from three subterranean environments, along with statistical analyses including principal component
analysis, I measured subsurface biosignatures associated with these biomineralization effects, including the presence of
trace elements, morphological characteristics, organic molecules, and amorphous crystal structures.
I also explored the optimization of a two-step LD-TOF-MS (L2MS) for the detection of organic molecules and other
biosignatures. I focused my efforts on characterizing the L2MS desorption IR laser wavelength dependence on organic
detection sensitivity in an effort to optimize the detection of high mass (≤100 Da) organic peaks. I analyzed samples
with an IR reflectance spectrometer and an L2MS with a tunable desorption IR laser whose wavelength range (2.7 – 3.45
microns) overlaps that of our IR spectrometer (1.6 – 3.6 microns), and discovered a IR resonance enhancement effect. A
correlation between the maximum IR absorption of organic functional group and mineral vibrational transitions – inferred
from the IR spectrum – and the optimal IR laser configuration for organic detection using L2MS indicates that IR
spectroscopy may be used to inform the optimal L2MS IR laser wavelength for organic detection. This work suggests that a
suite of instruments, particularly LD-TOF-MS and AOTF IR spectroscopy, has strong biosignature detection potential on a
future robotic platform for investigations of other planetary surfaces or subsurfaces.
Observing the Baryon Cycle in Hydrodynamic Cosmological Simulations
Jacob Vander Vliet, NMSU
An understanding of galaxy evolution requires an understanding of the flow of baryons in and out of a galaxy. The accretion of baryons is required for galaxies to form stars, while stars eject baryons out of the galaxy through stellar feedback mechanisms such as supernovae, stellar winds, and radiation pressure. The interplay between outflowing and infalling material form the circumgalactic medium (CGM). Hydrodynamic simulations provide understanding in the connection between stellar feedback and the distribution and kinematics of baryons in the CGM. To compare simulations and observations properly the simulated CGM must be observed in the same manner as the real CGM. I have developed the Mockspec code to generate synthetic quasar absorption line observations of the CGM in cosmological hydrodynamic simulations. Mockspec generates synthetic spectra based on the phase, metallicity, and kinematics of CGM gas and mimics instrumental effects. Mockspec includes automatic analysis of the spectra and identifies the gas responsible for the absorption. Mockspec was applied to simulations of dwarf galaxies at low redshift to examine the observable effect different feedback models have on the CGM. While the different feedback models had strong effects on the galaxy, they all produced a similar CGM that failed match observations. Mockspec was applied to the VELA simulation suite of high redshift, high mass galaxies to examine the variance of the CGM across different galaxies in different environments. The observable CGM showed little variation between the different galaxies and almost no evolution from z=4 to z=1. The VELAs were not able to generate a CGM to match the observations. The properties of cells responsible for the absorption were compared to the derived properties from Voigt Profile decomposition. VP modeling was found to accurately describe the HI and MgII absorbing gas but failed for high ionization species such as CIV and OVI, which do not arise in the assumed coherent structures. The technique of mock QAL is useful for testing the accuracy of the simulated CGM and for verifying observational techniques, but not for differentiating between feedback prescriptions in dwarf galaxies.
The Vulture Survey of MgII and CIV Absorbers: Feasting on the Bones of Spectra Left to Die
Nigel Mathes, NMSU
We present detailed measurements of the absorption properties and redshift evolution of MgII and CIV absorbers as measured in archival spectra from the UVES spectrograph at the Very Large Telescope (VLT/UVES) and the HIRES spectrograph at the Keck Telescope (Keck/HIRES) to equivalent width detection limits below 0.01 angstroms. This survey examines 860 high resolution spectra from various archival data sets representing 700 unique sightlines, allowing for detections of intervening MgII absorbers spanning redshifts 0.1 < z < 2.6 and intervening CIV absorbers spanning redshifts 1 < z < 5. We employ an accurate, automated approach to line detection which consistently detects redshifted absorption doublets. We observe three distinct epochs of evolution in the circumgalactic medium (CGM) as traced by MgII and CIV absorbers. At high redshifts, from 3 < z < 5, galaxies rapidly build up a metal enriched halo where, despite significant evolution in the ionizing background, the production of metals through star formation driven outflows dominates observed trends increasing the number of observed absorbers per redshift path length towards z = 3. At mid redshifts, from 2 < z < 3, a large cosmic increase in the global star formation rate drives large numbers of high column density outflows into the halos of galaxies. At this time, metal line absorption of all species is increased above all other epochs. At low redshifts, for z < 2, the universe becomes more quiescent in both star formation and ionizing background. Weak, low column density MgII absorbers proliferate, while strong MgII absorbers likely fragment or re-accrete onto their host galaxy. Strong CIV absorbers, at this time, still increase in number per absorption path, while their weaker counterparts begin to disappear. MgII and CIV absorbers appear to originate in star formation driven outflows, but their different evolutionary properties imply they represent two physically distinct phases of gas. These two phases comprise the CGM and contribute separately to the cycle of baryons into and out of galaxies.
Asteroseismology of Red Giants: The Detailed Modeling of Red Giants in Eclipsing Binary Systems
Jean McKeever, NMSU
Asteroseismology is an invaluable tool that allows one to peer into the inside of a star and know its fundamental stellar properties with relative ease. There has been much exploration of solar-like oscillations within red giants with recent advances in technology, leading to new innovations in observing. The Kepler mission, with its 4-year observations of a single patch of sky, has opened the floodgates on asteroseismic studies. Binary star systems are also an invaluable tool for their ability to provide independent constraints on fundamental stellar parameters such as mass and radius. The asteroseismic scaling laws link observables in the light curves of stars to the physical parameters in the star, providing a unique tool to study large populations of stars quite easily. In this work we present our 4-year radial velocity observing program to provide accurate dynamical masses for 16 red giants in eclipsing binary systems. From this we find that asteroseismology overestimates the mass and radius of red giants by 15% and 5% respectively. We further attempt to model the pulsations of a few of these stars using stellar evolution and oscillation codes. The goal is to determine which masses are correct and if there is a physical cause for the discrepancy in asteroseismic masses. We find there are many challenges to modeling evolved stars such as red giants and we address a few of the major concerns. These systems are some of the best studied systems to date and further exploration of their asteroseismic mysteries is inevitable.