Characterization of Biosignatures within Geologic Samples Analyzed using a Suite of in situ Techniques
Kyle Uckert, NMSU
I investigated the biosignature detection capabilities of several in situ techniques to evaluate their potential to
detect the presence of extant or extinct life on other planetary surfaces. These instruments included: a laser desorption
time-of- flight mass spectrometer (LD-TOF-MS), an acousto-optic tunable filter (AOTF) infrared (IR) point spectrometer, a
laser-induced breakdown spectrometer (LIBS), X-ray diffraction (XRD)/X-ray fluorescence (XRF), and scanning electron
microscopy (SEM)/energy dispersive X-Ray spectroscopy (EDS). I measured the IR reflectance spectra of several speleothems
in caves in situ to detect the presence of biomineralization. Microorganisms (such as those that may exist on other solar
system bodies) mediate redox reactions to obtain energy for growth and reproduction, producing minerals such as
carbonates, metal oxides, and sulfates as waste products. Microbes occasionally become entombed in their mineral
excrement, essentially acting as a nucleation site for further crystal growth. This process produces minerals with a
crystal lattice distinct from geologic precipitation, detectable with IR reflectance spectroscopy. Using a suite of
samples collected from three subterranean environments, along with statistical analyses including principal component
analysis, I measured subsurface biosignatures associated with these biomineralization effects, including the presence of
trace elements, morphological characteristics, organic molecules, and amorphous crystal structures.
I also explored the optimization of a two-step LD-TOF-MS (L2MS) for the detection of organic molecules and other
biosignatures. I focused my efforts on characterizing the L2MS desorption IR laser wavelength dependence on organic
detection sensitivity in an effort to optimize the detection of high mass (≤100 Da) organic peaks. I analyzed samples
with an IR reflectance spectrometer and an L2MS with a tunable desorption IR laser whose wavelength range (2.7 – 3.45
microns) overlaps that of our IR spectrometer (1.6 – 3.6 microns), and discovered a IR resonance enhancement effect. A
correlation between the maximum IR absorption of organic functional group and mineral vibrational transitions – inferred
from the IR spectrum – and the optimal IR laser configuration for organic detection using L2MS indicates that IR
spectroscopy may be used to inform the optimal L2MS IR laser wavelength for organic detection. This work suggests that a
suite of instruments, particularly LD-TOF-MS and AOTF IR spectroscopy, has strong biosignature detection potential on a
future robotic platform for investigations of other planetary surfaces or subsurfaces.
Outer Planets Update
Dr. Amy Simon, NASA
The Hubble Outer Planet Atmospheres Legacy (OPAL) program is a yearly program for observing each of the outer planets over two full rotations. Observations began with Uranus in 2014, adding Neptune and Jupiter in 2015 (Saturn will be included in 2018, after the end of the Cassini mission). These observations have provided interesting new discoveries in their own right, but are also now being combined with observations from a number of facilities, including NASA’s IRTF, Keck, the VLA, as well as the Kepler and Spitzer missions to further expand the breadth of science they contain. This talk will cover the latest observations for each of these planets and what we are learning from these data sets.
A Faint Flux-Limited LAE Sample at z = 0.3
Isak Wold, UT Austin
Observational surveys of Lya emitters (LAEs) have proven to be an efficient method to identify and study large numbers of galaxies over a wide redshift range. To understand what types of galaxies are selected in LAE surveys – and how this evolves with redshift – it is important to establish a low-redshift reference sample that can be directly compared to high-redshift samples. The lowest redshift where a direct Lya survey is currently possible is at a redshift of z~0.3 via the Galaxy Evolution Explorer (GALEX ) FUV grism data. Using the z~0.3 GALEX sample as an anchor point, it has been suggested that at low redshifts high equivalent width (EW) LAEs become less prevalent and that the amount of escaping Lya emission declines rapidly. A number of explanations for these trends have been suggested including increasing dust content, increasing neutral column density, and/or increasing metallicity of star-forming galaxies at lower redshifts. However, the published z~0.3 GALEX sample is pre-selected from bright NUV objects. Thus, objects with strong Lya emission but faint continuum (high-EW LAEs) could be missed. In this talk, I will present my efforts to re-reduce the deepest archival GALEX FUV grism data and obtain a sample that is not biased against high-EW LAEs. I will discuss the implications of this new sample on the evolutionary trends listed above.